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What is the Surface Tension of Vertrel® ?

Vertrel® products are the best choice in the industry for cleaning difficult shapes and awkard pieces. The reason for this success is the very low surface tension of the Vertrel® products.

A low surface tension means the solvent can get into tight spaces more easily than cleaning processes using solvents with high surface tensions (like aqueous systems). Vertrel® products can clean those spaces more effectively and more quickly without the time, expense and hassle of high-pressure pumps, extra heating costs and other complications of aqueous systems. In fact, the surface tension of the new Vertrel® products compares very favorably with the benchmark "safety solvent" of all time, Freon® TMS, but without any of the environmental problems.

Today's advanced BGA chips cause special cleaning problems. This photo shows the tight spacing beneath the chip where fluxes, pastes and other contamination can accumulate. The Vertrel® products, due to their low surface tension and high wetting index, can easily clean in these difficult circumstances. Photo courtesy Branson Ultrasonics

Here are the specifics:

The Surface Tension of Popular Vertrel® Solvents

Category

Solvent

Surface Tension in dyn/cm

HFC

MicroCare CF

15.0

Vertrel® CHD

19.4

MicroCare CMS

19.2

MicroCare CCA

18.8

Vertrel® MCA

15.2

Vertrel® MCA PLUS

16.1

Vertrel® SMT

15.5

Vertrel® XF

14.1

Vertrel® XM

14.1

Vertrel® XMS Plus

14.9

Vertrel® XDA

14.1

Vertrel® XP

15.1

Vertrel® XP10

14.1


The Surface Tension of Competing Solvents

Category

Solvent

Surface Tension in dyn/cm

Alcohol

Ethyl Alchol

22.3

HCFC-225

Asahi 225

16.2

Brominated

Typical Results

26.3

HFE Solvents

HFE-7100

19.0

HCFC-141b

Genesolv® 2004 (-141b plus Methanol)

18.5

CFC-113

Freon® TMS (-113 plus Methanol)

17.4

Chlorinated

1,1,1-TCA

25.9

Aqueous

Water

72.8

But there is a better measurement of the cleaning efficiency of a solvent. A smarter, more comprehensive approach is to combine the three most critical factors into a single index. DuPont recommends using the density of the solvent, the viscosity of the solvent and the surface tension into a cleaning index. DuPont calls this the wetting index. With the wetting index, a higher score produces better cleaning.

In particular, the wetting index is a superior predictor when comparing particulate cleaners. It's a better gauge to use when selecting a solvent for applications in which the object is not to dissolve the contamination but to float it away.

DuPont has computed this index for a number of popular cleaners. The results confirm popular experience: a heavy, dense solvent like Vertrel® with a low surface tension and low viscosity will clean better than anything else on the market today. Here's how the numbers rack up:

The Wetting Indices of Popular Solvents

Type of Solvent

Name

Density

Surface
Tension
in dyn/cm

Viscosity

Wetting
Index

CFC-113

Freon® TF

1.48

17.3

0.70

122

Chlorinated

TCA

1.32

25.9

0.79

65

Alcohol

IPA

0.79

21.7

2.40

15

Aqueous

DI Water

0.997

72.8

1.00

14

DI Water + Surf

0.998

29.7

1.08

31

HFC

Vertrel¨ XF

1.58

14.1

0.67

167

Vertrel¨ XP

1.53

14.2

0.68

158

As mentioned above, when comparing wetting indices the higher score will deliver better cleaning. The formula for computing the wetting index is:

Wetting Index = (Density x 1000)/( Surface Tension x Viscosity)

So here's a great answer: when it comes to tough cleaning problems, Vertrel® specialty fluids are the ideal choice. These are great replacements for ozone-depleting solvents such as CFC-113, 1,1,1-trichloroethane, HCFC-141b, n-propyl bromide (nPB), HFE solvents and HCFC-225, as well as high-global-warming solvents such as perfluorocarbons (PFCs).


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The term "Vertrel" is a registered trademark of DuPont Corp. and is used with permission.

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